Ch 6

Properties of Molecules

(outline, continued)

Van der Waals Forces (between molecules)

 

1. Dipole-Dipole Forces (between polar molecules)

 (see board)

 

 

 

 

 

2. London Forces

 (see board)

 

 

 

3. Hydrogen Bonds (between molecules)

Very strong dipole-dipole force which occurs when H is bonded to N, O, or F (small & electroneg.)

 (see board)

 

 

 

 

  

Relative Strength of Forces

 

Force

Energy, kJ

Strength

Covalent bonding

100 - 1000

Strong

Ionic bonding

100 - 1000

Strong

Metallic bonding

100 - 1000

Strong

Hydrogen bonding

10 - 40

Moderate

Van der Waals

0.1 - 10

Weak

 

 

Examples

 

NaCl

 

 

C2H4 (ethylene)

 

 

(CH2CH2)n (polyethylene)

 

 

W

 

 

C(diamond)

 

 

B

 

 

C12H22O11 (sucrose)