Atomic Structure
(outline, part 1)
Electromagnetic Radiation
Light is just one form of electromagnetic radiation. The relationship between the frequency of light and the wavelength is given by the equation:
c = ln
c = 3.00 X 108 m/s = speed of light
l = wavelength
n = frequency
wavelength and frequency are ____________ proportional
The Photoelectric Effect
Einstein (1905)
(ROY G BIV)
Observations:
1. Light with a frequency less than that of red light shows ________________________________________
2. If the freq. is greater than or equal to that of red light, ____________________________________________
3. The kinetic energy of the ejected electrons _____________________________________
Einstein's Hypothesis:
Light has a dual nature:
Wave-Particle Nature of Light
Quotation: "Anyone who is not shocked by quantum theory has not understood
it."
-Niels Bohr
The Delayed Choice Experiment (Scientific American Jan. 1988, p. 46)

Experimental setup.
Procedure:
1. The laser is fired and one photon is sent into the beam splitter.
2. If the photon behaves like a __________ it will take either path A or A' as it leaves the beam splitter.
3. If the photon behaves like a _________ it will "split" in two and take both paths and interfere with itself.
4. After the photon leaves the beam splitter the switch is ______________.
5. If the switch is turned to the _____ position the photon either takes path A or path A' and is detected by the photodetector. It behaves as a _____________________
6. If the switch is turned to the _______ position the photon takes both paths and produces an interference pattern. It behaves as a _________.
How does the photon decide how to behave?
Possible Explanations
1. The photon knows how the switch will be turned in advance and makes a decision before leaving the beam splitter.
2. The nature of the photon is indeterminate until the switch is turned and an observation is made: the photon becomes a wave or becomes a particle.
3. God controls both the "decision" of the photon and the experimenter.
Atomic Emission Spectrum of Hydrogen
Continuous spectrum (electric arc; light bulb) vs. line spectrum (hydrogen lamp)
How can we explain the line spectrum of hydrogen?
The Bohr Model
Niels Bohr (1913)
Assumptions:
1. The electron in the hydrogen atom orbits around the nucleus with a ____________.
problem:_______________
2. The energy of the electron is ____________________________________-
Energy levels and the corresponding orbits in the Bohr model.
n = quantum no.:
3. Energy transitions
E2 - E1 = DE = hn = energy of the photon emitted
Problem: the Bohr model only works for H
Bohr model: